VEctomer® Vinyl Ether

VE 5015 Monomer

 
 

Composition

VE 5015 - vinyl ether terminated aromatic ester monomer: HBVE trimellitate;

Tris(4-vinyloxybutyl)trimellitate,

Average functionality = 2.8

Molecular weight = 504.58 (g/mole)

Formula: C27H36O9

CAS # 196109-17-8

Description

VE 5015 is a trifunctional aromatic diluent monomer. It is a low viscosity clear liquid that is designed to improve cross-link density of coating inks, adhesives and other radiation cured formulations.

Product/Application Benefits

  • Fast cure speed
  • Low initiation energy
  • High gloss
  • Toughness
  • Solvent resistance
  • Low viscosity
  • Low odor

Typical Properties

Viscosity (cps @22 °C, Brookfield) 253
Color, Gardner 1 max.
Flash Point, Penskie, °F 341
Min. UV cure dose, AR3SSbF6, 2pph, mJ/cm² 50
Surface Tension, dynes/cm 39
Refractive Index 1.50861
Functionality 2.8
Specific Gravity (H2O = 1) 1.13
Viscosity / Temperature

Photoinitiators

Photoinitiators – Triarylsulfonium salts

Union Carbide UVI-6974, UVI-6990, 3M FX512, Degussa KI-85.

Photoinitiator level - 0.3 - 2.0% (w/w), for coatings up to 6 mil thickness.

Notes

1) UVI-6990 gives slightly slower cure speeds than UVI-6974. However, UVI-6990 is recommended in color sensitive applications.

2) Irganox 1076 (1% w/w) can be used to reduce discoloration on heating.

3) Gentle heating often improves photoinitiator solubility.

Recommended Curing Conditions

Formulations containing VE 5015 along with VEctomerä oligomers and initiator may be UV-cured at 50 to 500 mJ/cm² (approx. 500 to 50 fpm) with two 200 watt/inch medium pressure mercury arc lamps). Vinyl ether formulations containing initiators may be cured with electron beam irradiation at 1 to 4 mrad.

Vinyl ethers cure by an acid-catalyzed reaction. Basic components such as amines in the formulations should be avoided.

Curing is not inhibited by oxygen but may be inhibited by high atmospheric humidity. Inhibition (if any) will depend on the formulation, substrate and temperature in the curing zone.

Storage and Handling

May be heated up to 65 °C for short periods to facilitate mixing and handling.

Mixtures containing initiator should be protected from prolonged exposure to fluorescent lights or sunlight.

Materials should be stored at room temperature, away from sunlight or UV radiation. Please refer to MSDS for additional information regarding safe handling and environmental precautions.

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The information contained herein is true and accurate to the best of our knowledge. No warranty or guarantee is expressed or implied regarding the accuracy of such data. It is the user’s responsibility to determine the suitability for his own use of the product(s) described herein. Nothing herein shall constitute permission, inducement, or recommendation to practice any invention covered by any patent owned by Morflex, Inc. Or by others, nor as a recommendation to use any product or to practice any process in violation of any law or government regulation.

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This Page Last Updated Thursday, 10 March 2005 

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